| 两种1,2,3-三唑衍生物的配合物合成策略:晶体结构和表面分析 |
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| 引用本文： | 冯超,张舵,周士艳,陈金梅,左泽浩,赵红.两种1,2,3-三唑衍生物的配合物合成策略:晶体结构和表面分析[J].无机化学学报,2016,32(7):1215-1222. |
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| 作者姓名： | 冯超 张舵 周士艳 陈金梅 左泽浩 赵红 |
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| 作者单位： | 东南大学化学化工学院, 南京 211189,东南大学化学化工学院, 南京 211189,东南大学化学化工学院, 南京 211189,东南大学化学化工学院, 南京 211189,东南大学化学化工学院, 南京 211189,东南大学化学化工学院, 南京 211189 |
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| 摘 要： | 在不同反应条件下反应得到了两种1，2，3-三唑衍生物的配合物Co（H2O）6]Co（L1）3]2·4H2O（1）和Cu（L2）2（2）（HL1=5-methyl-1-phenyl-1H-1，2，3-triazole-4-carboxylic acid；HL2=1-（4-iodophenyl）-5-methyl-1H-1，2，3-triazole-4-carboxylic acid）。通过X射线单晶衍射和红外光谱确定了晶体结构，同时对配合物1和2进行了表面作用分析（Hirshfeld surface analysis），在二维指纹图谱中可以清楚的看到配合物中的主要分子间作用。
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| 关 键 词： | 1H-1 2 3-三唑衍生物 晶体结构 表面分析 二维指纹区 |
| 收稿时间： | 2015/12/12 0:00:00 |
| 修稿时间： | 5/2/2016 12:00:00 AM |
A Synthetic Strategy for Two Complexes with 1, 2, 3-Triazole Derivatives: Crystal Structures and Hirshfeld Surface Analysis |
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| FENG Chao,ZHANG Duo,ZHOU Shi-Yan,CHEN Jin-Mei,ZUO Ze-Hao and ZHAO Hong.A Synthetic Strategy for Two Complexes with 1, 2, 3-Triazole Derivatives: Crystal Structures and Hirshfeld Surface Analysis[J].Chinese Journal of Inorganic Chemistry,2016,32(7):1215-1222. |
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| Authors: | FENG Chao ZHANG Duo ZHOU Shi-Yan CHEN Jin-Mei ZUO Ze-Hao and ZHAO Hong |
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| Institution: | School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China,School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China |
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| Abstract: | Two new complexes Co(H2O)6]Co(L1)3]2·4H2O (1) and Cu(L2)2 (2) were synthesized by 1H-1,2,3-triazole acid derivatives under various reaction conditions(HL1=5-methyl-1-phenyl-1H-1,2,3-triazole-4-carboxylic acid; HL2=1-(4-iodophenyl)-5-methyl-1H-1,2,3-triazole-4-carboxylic acid). The crystal structures have been established by single-crystal X-ray diffraction, and characterized by FTIR. Hirshfeld surface analysis for complexes 1 and 2 indicate that the 2D fingerprint plots obviously show the main intermolecular interactions in both complexes. |
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| Keywords: | 1H-1 2 3-triazole acid derivatives crystal structure Hirshfeld surface analysis 2D fingerprint plots |
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