Flexible self-assembling porphyrin supramolecules |
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Authors: | Johnstone Ken D Yamaguchi Kentaro Gunter Maxwell J |
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Affiliation: | School of Biological, Biomedical and Molecular Sciences, University of New England, Armidale, NSW 2350, Australia. |
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Abstract: | The design and chemical synthesis of a series of hybrid flexible self-assembling supramolecules utilising both crown ether-naphthalene diimide host-guest chemistry and metalloporphyrin-pyridyl coordination is discussed. The resulting compound structures and dynamics are probed using a variety of techniques, including diffusion ordered NMR spectroscopy (DOSY) and cold-spray ionisation mass spectrometry (CSI-MS). |
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