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Sn-Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride (or Sodium Borodeuteride)
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关 键 词:锡催化剂 不对称还原反应 碳酰基 硼氢化钠 手性配合体 羰基化合物

Sn‐Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride (or Sodium Borodeuteride)
Gang Zhao,Jian‐Bing Hu. Sn‐Mediated Catalytic Asymmetric Reduction of Carbonyl Groups by Sodium Borohydride (or Sodium Borodeuteride)[J]. Chinese Journal of Chemistry, 2003, 21(7): 819-823. DOI: 10.1002/cjoc.20030210721
Authors:Gang Zhao  Jian‐Bing Hu
Abstract:Two remarkable reducing agents NaBH4 (or NaBD4)/SnCl2(or SnCl4·2Et2O) with chiral ligands are applied to the asymmetric reduction of carbonyl compounds with excellent chemical yields and enantioselective excesses.
Keywords:asymmetric reduction  chiral ligand  carbonyl compound
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