IR spectroscopic studies of Ru3(CO)12 interaction with disperse metallic palladium supported on SiO2 |
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| Authors: | Yu A Ryndin L V Gorodova O V Tyunina A A Davydov and Yu I Yermakov |
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| Institution: | (1) Institute of Catalysis, Novosibirsk, USSR |
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| Abstract: | IR spectroscopic studies of the interaction of Ru3(CO)12 with reduced Pd/SiO2 have revealed that at 298 K Ru3(CO)12 chemisorbs on the surface of metallic palladium and is partly oxidized by OH-groups of SiO2. Subsequent reduction by hydrogen leads to the formation of bimetallic clusters possessing nonadditive chemisorption properties.
        -            Ru3(CO)12      Pd/SiO2.  298 Ru3(CO)12   ,  OH- SiO2.  ,    .
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