| Synthesis and Characterisation of Water-Soluble Carboxymethyl-Cyclodextrin Polymer as Capillary Electrophoresis Chiral Selector |
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| 引用本文： | Xue Yan SHI, Rui Fang FAN, Yue Qin ZHANG, Jun Ling GU, Ruo Nong FU( College of Chemical Engineering and Material Science Beijing Institute of Technology,Beijing 100081). Synthesis and Characterisation of Water-Soluble Carboxymethyl-Cyclodextrin Polymer as Capillary Electrophoresis Chiral Selector[J]. 中国化学快报, 2000, 0(1) |
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| 作者姓名： | Xue Yan SHI Rui Fang FAN Yue Qin ZHANG Jun Ling GU Ruo Nong FU( College of Chemical Engineering and Material Science Beijing Institute of Technology Beijing 100081) |
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| 作者单位： | College of Chemical Engineering and Material Science Beijing Institute of Technology，Beijing 100081 |
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| 摘 要： | Cyclodextrin (CD) and its water-soluble derivatives have been used as chiral selectors incapillary electrophoresis successfully. Among them, the water-soluble CD polymerperforms intramolecular synergistic effect in CE chiral separation and thecarboxymethyl-CD (CM-CD) migrates in the opposite direction of the electroosmoticflow because of its negative charge in water. It is interesting to synthesizecarboxymethyl-CD polymer (CM-CD polymer), which has properties of both the neutralCD poly…
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Synthesis and Characterisation of Water-Soluble Carboxymethyl-Cyclodextrin Polymer as Capillary Electrophoresis Chiral Selector |
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| Xue Yan SHI, Rui Fang FAN, Yue Qin ZHANG, Jun Ling GU, Ruo Nong FU. Synthesis and Characterisation of Water-Soluble Carboxymethyl-Cyclodextrin Polymer as Capillary Electrophoresis Chiral Selector[J]. Chinese Chemical Letters, 2000, 0(1) |
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| Authors: | Xue Yan SHI Rui Fang FAN Yue Qin ZHANG Jun Ling GU Ruo Nong FU |
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| Abstract: | The water-soluble carboxymethyl-cyclodextrin polymer (CM-CD polymer) was synthesized and used as capillary electrophoresis chiral selector. Verrapamil and thiopentorusodium were well separated using CM-CD polymer as chiral selector. |
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| Keywords: | Carboxymethyl-cyclodextrin polymer capillary electrophoresis chiral selector. |
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