Structure and Semiconducting Character of a Polymeric Iodoplumbate Coordination Complex |
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| Authors: | SONG De-Sheng LIU Chang-Chun CHEN Heng-Jun SU Dong-Po FU Zhi-Yong |
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| Affiliation: | Key Laboratory of New Energy Technology for Guangdong Universities, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China |
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| Abstract: | A new polymeric iodoplumbate complex [Zn(DMF)6][Pb2I6] 1 has been prepared and characterized by elemental analysis and single-crystal X-ray analysis. Its structure contains infinite iodoplumbate chains constructed by the [PbI5] subunit. EHT crystal orbital calculation and the experimental results show that this material is an unconventional semiconductor and the electrical character is associated with its structural feature. |
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| Keywords: | iodoplumbate coordination polymer structure and characterization semiconducting property |
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