| Structure and Luminescence Property of a Hexanuclear Silver（Ⅰ） Cluster Containing Benzaldehyde Thiosemicarbazone |
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| 作者姓名： | SUN Qiao-Zhen |
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| 作者单位： | Department of Materials Chemistry, School of Materials Science and Engineering; Key Laboratory of Nonferrous Metal of Ministry of Education, Central South University, Changsha 410083, China |
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| 基金项目： | supported by the Postdoctoral Science Foundation of Central South University |
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| 摘 要： | A new hexanuclear silver (I) compound 2 containing thiosemicarbazone with the group of benzene was synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analysis and fluorescence spectrum. The title compound crystallizes in triclinic, space group P with a = 11.611(3), b = 15.610(5), c = 15.624(7) , α = 113.942(6), β = 104.520(6), γ = 104.230(4)°, V = 2304.1(14) 3, C60H77Ag6N22O4.5S6, Mr = 2018.02, Dc = 1.454 g/cm3, μ(MoKα) = 1.435 mm-1, F(000) = 1005, Z = 1, the final R = 0.0468 and wR = 0.1474 for 6608 observed reflections (I > 2σ(I)). In the structure, the S atom of the ligand L2 (L2 = benzaldehyde thiosemicarbazone) served as a triply bridged chelator to connect the six silver atoms into a Ag6L26 cluster. The luminescence property of compound 2 was investigated at room temperature.
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| 关 键 词： | 缩氨基硫脲 群集结构 银（I） 发光性能 苯甲醛 标题化合物 属性 结构表征 |
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