含杯芳烃聚合物的合成与应用

杯芳烃在主客体化学中是继冠醚和环糊精之后被广泛关注的第三代主体分子，能够选择性地与客体分子或离子形成络合物。近年来，含杯芳烃聚合物逐渐受到人们的重视。结合聚合物稳定性好，易于加工的特性，含杯芳烃聚合物将有望被开发成为新型功能高分子材料。本文详细介绍了含杯芳烃聚合物的合成及其应用。

Synthesis and Application of Calixarene Containing Polymers

Calixarenes are highly versatile scaffolds for the design of 3-D cavities, and have been regarded as the third generation of host molecule after crown ethers and cyclodextrins in supermolecular chemistry, which can selectively form complexes with guest molecules or ions. Recently, calixarene containing polymers have attracted much attention. Due to the good stability and machinability of polymer materials, calixarene containing polymers are expected to be developed as novel functional materials, which have been widely studies in ion selective electrodes and membranes, chemical and biochemical sensors and selective extraction of ions and neutral molecules. Based on the chain structures, there are three kinds of calixarenes containing polymers: calixarene in polymer backbone, calixarene as polymer side group and star polymer with a calixarene core. In this paper, the recent progress on the synthesis and application of calixarene containing polymers is reviewed.