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Electrolysis of Nitro Compound Salts: Application in Ketone Synthesis |
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| Authors: | Yu N Ogibin A I Ilovaiskii V M Merkulova G I Nikishin |
| Institution: | (1) Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia |
| Abstract: | One-pot electrochemical method of synthesis of ketones, diketones, and esters of monoketo- and diketoalkanoic acids is elaborated. This method is based on the diaphragmless galvanostatic electrolysis of Na salts of secondary nitro compounds—derivatives of nitrohydrocarbons, nitroketones, and esters of nitrated alkanoic acids—in methanol. |
| Keywords: | primary and secondary nitrohydrocarbons esters of nitroalkanoic acids 5-nitroheptane-2-on 2-nitrocycloalkanons nitro compound salts electrolysis mechanism of process electrosynthesis ketones diketones esters of monoketo- and diketoalkanoic acids diketoalkandioic acid esters |
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