| Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS |
| |
| 作者姓名： | Jian Jun ZHAI Wei YING Fan Zhi ZHA Yao Zu CHEN |
| |
| 作者单位： | National Laboratory of Applied Organic Chemistry at Lanzhou University，Lanzhou 730000 |
| |
| 摘 要： | Itiswellknownthattheallylc0mP0undsexhibitavariety0finterestingrearrangementreacti0ns.Intheliquidphase,temPerature-inducedClaisenrearrangement,cyclizationreactionsandacid-induced0rthoClaisenrearrangementsofallylphenyletherhavebeenstUdiedextensively.'-'However,theClaisenrearrangementinthegasphasewasrepoftedonlyrecelltly,includingtheprotonatedallylphenyletherandN-allylanilineunderpositivecheITilcalionizationcondition4",thedeprotonatedallylphenylacetateanddeprotonatedallylphenyletherundernegati…
|
Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS |
| |
| Jian Jun ZHAI, Wei YING, Fan Zhi ZHA, Yao Zu CHEN.Detection of Claisen Rearrangement Occurring in Allyl Phenyl Ether by in situ GC/MS[J].Chinese Chemical Letters,1998(4). |
| |
| Authors: | Jian Jun ZHAI Wei YING Fan Zhi ZHA Yao Zu CHEN |
| |
| Institution: | Jian Jun ZHAI, Wei YING, Fan Zhi ZHA0, Yao Zu CHEN |
| |
| Abstract: | We report here a new strategy for revealing the Claisen rearrangement of allyl phenyl ether occurring in the gas phase by in situ GC/MS technique. The Ciaisen rearrangement has been observed when allyl phenyl ether passed through the capillary column at certain temperatures. The relative proportion of rearrangement products is dependent on the temperature of the capillary column and the substituents on the phenylring. |
| |
| Keywords: | in situ GC/MS allyl phenyl ether Claisen rearrangement |
| 本文献已被 CNKI 等数据库收录！ |
