Kinetics and mechanism of the catalytic hydration of propylene oxide |
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Authors: | R. Z. Shaikhutdinov L. A. Petukhov N. V. Sapunov Kh. E. Kharlampidi A. A. Petukhov |
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Affiliation: | 1.Nizhnekamsk Institute of Chemical Technology,Nizhnekamsk,Tatarstan, Russia;2.Kazan State Technological University,Kazan,Tatarstan, Russia;3.Mendeleev University of Chemical Technology of Russia,Moscow,Russia |
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Abstract: | The kinetics of propylene oxide hydration in the presence of bis(ethane-1,2-diol)molybdate is reported. A mathematical description of PO disappearance and propylene glycol formation is suggested. The most probable scheme for the process is presented. The basic kinetic constants are calculated. |
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