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Neutron activation analysis by the monostandard method
Authors:G Delcroix  J Cl Philippot
Institution:1. CNRS Centre de Recherches Archéologiques, 23 rue du Maroc, 75019, Paris, (France)
2. CEA Département de Protection, Labo 501, 91400, Orsay, (France)
Abstract:The “absolute” quantitative processing of complex gamma-ray spectra has been made possible by the use of high resolution detectors and by irradiation with a well thermalized neutron flux. So, the simultaneous determination of many stable elements, either major or trace components is possible without destruction of the sample. The results of measurements on the irradiated samples show a threefold recurrence: (1) each element appears as often as it possesses activable isotopes, under the form of ray emitting nuclides, (2) each nuclide is determined as often as it presents ditinct emission lines, (3) all measurements are repeated in time. So under these conditions and with an original computer data processing, neutron activation analysis is a powerful analytical tool. The recurrence of the results gives access to the interpretation of the origin of various errors which consequently are better estimated. If applied to the study of ancients ceramics, this method should perhaps allow to evaluate the relationship between the geochemical imprint characteristic of the artifact and the original location, or even workshop.
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