Transformations ofmyo-inositol hexa-O-nitrate under the action of amines |
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| Authors: | Y. E. Kuznetsov N. L. Sukhov F. V. Pichugin B. G. Ershov |
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| Affiliation: | (1) Institute of Chemistry and Chemical Technology, National Academy of Sciences of Kyrghyz Republic, 720071 Bishkek, Kyrghyz Republic;(2) Institute of Physical Chemistry, Russian Academy of Sciences, 117915 Moscow, Russian Federation |
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| Abstract: | Reactions ofmyo-inositiol hexa-O-nitrate with ammonia and primary amines yield tetrahydroxy-1,4-benzoquinone derivatives,viz., its tetraammonium salt and its diimines, respectively. Reactions with secondary and tertiary amines give salts of rhodizonic acid, which are converted into salts of croconic acid under certain conditions. The reactions with secondary amines involve intermediate formation of radical species, which were dectected by ESR spectroscopy. A scheme for the chemical transformations ofmyo-inositol hexa-O-nitrate under the action of amines was proposed.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2962–2967, December, 1996. |
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| Keywords: | myo-inositol hexanitrate amines salts of rhodizonic and croconic acid tetrahydroxy-1,4-benzoquinone derivatives scheme of reaction |
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