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Density and Speed of Sound for Binary Mixtures of a Cyclic Ether with a Butanol Isomer
Authors:I. Gascón  S. Martín  P. Cea  M. C. López  F. M. Royo
Affiliation:(1) Departamento de Química Orgánica-Química Física, Área de Química Física, Facultad de Ciencias, Universidad de Zaragoza, Campus Plaza San Francisco, 50009 Zaragoza, España
Abstract:Densities and speeds of sound of the binary mixtures 1,3-dioxolane + 1-butanol, 1,3-dioxolane + 2-butanol, 1,4-dioxane + 1-butanol, and 1,4-dioxane + 2-butanol have been measured at 25 and 40°C. The excess molar volumes and excess isentropic compressibility coefficients were calculated from experimental data and fitted to a Redlich–Kister polynomial function. Results were analyzed in terms of molecular interactions and compared with literature data.
Keywords:Density  speed of sound  excess molar volume  isentropic compressibility coefficient  cyclic ether, butanol  1,3-dioxolane  1,4-dioxane  butanols
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