AB(~1∏,J)+C(~(s_1)l_(1j_1))→AB(~1∏,J′)+C(~(s_1)l_(1j_1)′)+C(~(s_2)l_(2j_2)′)电子和转动传能的电子量子干涉

在我们以前的理论研究中,给出了AB(1∏,J) C(sli)→AB(1∏,J′) C(slj′)碰撞诱导电子和转动传能的理论模型.为了进一步在理论上研究AB(1∏,J) C(s1l1j1)→AB(1∏,J′) C(s1l1j1′) C(s2l2j2′)的电子和转动传能的电子量子干涉,以波恩奥本海默近似为基础,考虑各项异性Lennard-Jones相互作用势,给出了其理论模型.得出了衡量干涉程度的干涉角,对完全干涉的情况进行了讨论,得出了决定几率比的因素,此理论模型对理解和进行这种类型的实验是很重要的.

Electronic quantum interference on the electronic and rotational energy transfer of AB(1∏, J)+C(s1l1j1)→AB(1∏, J′)+C(s1l2j2)

In our previous theoretical study, the theoretical model of the collision-induced electronic and rotational energy transfer of AB(1∏, J)+C(sli)→AB(1∏, J′)+C(slj′) was presented. To further study theoretically the electronic quantum interference on the electronic and rotational energy transfer of AB(1∏, J)+C(s1l1j1)→AB(1∏, J′)+C(s1l1j1′)+C(s2l2j2),a theoretical model is presented, based on the time dependent first order Born approximation, taking into account the Lennard-Jones interaction potential. The interference angle, which measures the degree of the interference, is derived. The case of the complete interference is discussed. The factors that ratio of the probabilities depends on are obtained. This theoretical model is important to understand and perform the kind of experiment.