Enantiospecific synthesis of (S)-(+)-3-methylheneicosan-2-one, an analog of the sex pheromone of the German cockroach (Blatella germanica L.) from (?)-(1R,4S)-menthone |
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| Authors: | G Yu Ishmuratov M P Yakovleva R Ya Kharisov I M Muslimova R R Muslukhov R L Safiullin G A Tolstikov |
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| Institution: | (1) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | An enantiospecific synthesis of (S)-(+)-3-methylheneicosan-2-one, an analog of the sex pheromone of the German cockroach (Blatella germanica L.), was carried out through selective transformations of (3R,6S)-3,7-dimethyloctane-6-olide obtained from (−)-menthonevia the Baeyer—Villiger reaction.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1071–1073, May, 1997. |
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| Keywords: | (S)-(+)-3-methylheneicosan-2-one pheromone analog (− )-(1R 4S)-menthone (3R 6S)-3 7-dimethyloctane-6-olide Baeyer— Villiger Wittig and Wacker— Tsuji reactions |
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