Generation of a triplet diradical from a donor-acceptor cross conjugate upon acid-induced electron transfer |
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| Authors: | Sandberg Mats O Nagao Osami Wu Zhikun Matsushita Michio M Sugawara Tadashi |
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| Institution: | Department of Basic Science, Graduate School of Arts & Sciences, The University of Tokyo, Komaba, Meguro-Ku, Tokyo 153-8902, Japan. |
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| Abstract: | Enhancement of the electron acceptor ability of a para-quinodiimine unit by double protonation leads to the proton-induced intramolecular electron transfer from the donor unit to the cross-conjugated acceptor, giving rise to ground state triplet diradical reversibly. |
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