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Addition of hydrogen bromide to 3,3-dichloropropene in presence of benzoyl peroxide
Authors:R. Kh. Freidlina  M. Ya. Khorlina  A. N. Nesmeyanov
Affiliation:(1) Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR
Abstract:Summary When hydrogen bromide reacts with 3,3-dichloropropene in presence of benzoyl peroxide, homolytic rearrangement of radicals occurs (CHCl2CHCH2Br rarr CHClCHCl-CH2Br) with formation of 1-bromo-2,3-dichloropropane.
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