Intensities of line features in vibration-rotational bands 2–0 to 6–0 of NO XΠ<sub><i>r</i></sub> and experimental evaluation of a radial function for electric dipolar moment期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Intensities of line features in vibration-rotational bands 2–0 to 6–0 of NO XΠ_r and experimental evaluation of a radial function for electric dipolar moment

Authors:	Yuan-Pern Lee Swee-Lan Cheah J.F. Ogilvie

Affiliation:	^aDepartment of Applied Chemistry and Institute of Molecular Science, National Chiao Tung University, 1001 Ta-Hsueh Road, Hsinchu 30010, Taiwan ^bInstitute of Atomic and Molecular Sciences, Academia Sinica, Taipei 106, Taiwan ^cDepartment of Chemistry, National Tsing Hua University, 101, Section 2, Kuang Fu Road, Hsinchu 30013, Taiwan ^dEscuela de Quimica, Universidad de Costa Rica, Ciudad Universitaria Rodrigo Facio, San Pedro de Montes de Oca, San Jose 2060, Costa Rica

Abstract:	We measured the strengths of individual line-like features, representing unresolved Λ doublets, in vibration-rotational bands 2–0 to 6–0 of ¹⁴N¹⁶O within each substate of electronic ground state X²Π_1/2,3/2 in mid and near infrared regions. Analyses of these data to derive values of matrix elements for vibrational transitions enabled production of a radial function for electric dipolar moment, containing seven parameters, that satisfactorily reproduces the intensities of about 700 such features for vibrational states up to ν = 6.

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