| 三苯基锡(Ⅳ)N-烃基哌嗪氨荒酸酯配合物的合成、表征、性质和Ph3SnS2CN(C2H4)2NCH3的晶体结构 |
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| 引用本文： | 尹汉东,薛绳才,王传华. 三苯基锡(Ⅳ)N-烃基哌嗪氨荒酸酯配合物的合成、表征、性质和Ph3SnS2CN(C2H4)2NCH3的晶体结构[J]. 无机化学学报, 2005, 21(4): 531-534 |
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| 作者姓名： | 尹汉东 薛绳才 王传华 |
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| 作者单位： | 聊城大学化学系,聊城,252059 |
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| 基金项目： | 国家自然科学基金(No.20271025)，山东省自然科学基金(No.L2003B01)。 |
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| 摘 要： | Six triphenyltin(Ⅳ)N-alkylpiperazinyldithiocarbamates have been synthesized by the reaction of triphenyltin chloride with N-alkylpiperazinyldithiocarbamates and characterized by elemental analysis, UV, IR and 1H NMR. The crystal structure of Ph3SnS2CN(C2H4)2NCH3(1) has been determined by X-ray single crystal diffraction. The crystal of the compound 1 belongs to triclinic with space group P1, a=1.033 56(18) nm, b=1.148 8(2) nm, c=1.191 6(2) nm, α=66.282(2)°, β=78.756(2)°, γ=67.476(2)°， Z=2, V=1.195 2(4) nm3, Dc=1.460 g·cm-3, μ=1.256 mm-1, R=0.025 1, wR=0.058 3. The structure shows a distorted tigonal bipyramidal configuration with five-coordination for the central tin atom. CCDC: 240375.
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| 关 键 词： | 三苯基锡； N-烃基哌嗪氨荒酸酯； 合成； 晶体结构 |
| 文章编号： | 1001-4861(2005)04-0531-04 |
| 收稿时间： | 2004-07-12 |
| 修稿时间： | 2004-07-12 |
Synthesis, Characterization and Properties of Triphenyltin N-alkylpiperazinyldithiocarbamate and Crystal Structure of Ph3SnS2CN(C2H4)2NCH3 |
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| YIN Han-Dong,XUE Sheng-Cai and WANG Chuan-Hua. Synthesis, Characterization and Properties of Triphenyltin N-alkylpiperazinyldithiocarbamate and Crystal Structure of Ph3SnS2CN(C2H4)2NCH3[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(4): 531-534 |
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| Authors: | YIN Han-Dong XUE Sheng-Cai WANG Chuan-Hua |
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| Affiliation: | Department of Chemistry, Liaocheng University, Liaocheng 252059,Department of Chemistry, Liaocheng University, Liaocheng 252059 and Department of Chemistry, Liaocheng University, Liaocheng 252059 |
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| Abstract: | |
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| Keywords: | triphenyltin N-alkylpiperazinyldithiocarbamate synthesis crystal structure |
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