Scanning probe microscopy of adsorption layers of sodium polystyrenesulfonate/dodecyltrimethylammonium bromide complexes |
| |
| Authors: | A. V. Akentiev A. Yu. Bilibin I. M. Zorin S. -Y. Lin G. Loglio R. Miller B. A. Noskov |
| |
| Affiliation: | 1.Department of Chemistry,St. Petersburg State University,St. Petersburg,Russia;2.Chemical Engineering Department,National Taiwan University of Science and Technology,Taipei,Taiwan;3.Dipartimento di Chimica Organica,Universita degli Studi di Firenze,Sesto Fiorentino, Firenze,Italy;4.MPI für Kolloid- und Grenzfl?chenforschung Wissenschaftspark Golm,Golm,Germany |
| |
| Abstract: | Scanning probe microscopy is used to study adsorption films of sodium polystyrenesulfonate/dodecyltrimethylammonium bromide complexes, which are transferred from aqueous solution surfaces to the mica surface by the Langmuir-Blodgett method. It is established that the results obtained at surfactant concentrations below critical micelle concentration agree with the conclusions on the structure of the films dased on the data of the dilatational surface rheology (Noskov, B.A., Loglio, G., Miller, R., J. Phys. Chem. B, 2004, vol. 108, p. 18615). At low concentrations of the low-molecular-mass surfactant, a thin adsorption film containing a large number of holes is formed on the surface of an aqueous solution. As the surfactant concentration is increased to reach the region of a dramatic reduction in the dynamic surface elasticity, the morphology of the film drastically changes; i.e., dense three-dimensional aggregates are formed on the solution surface. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
