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Reaction of dithiomalonic acid dianilide with substituted acetylenic ketones
Authors:V N Elokhina  T I Yaroshenko  A S Nakhmanovich  L I Larina  S V Amosova
Institution:(1) Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia
Abstract:The reaction of dithiomalonic acid dianilide with 1-benzoyl(2-thienyl, 2-furoyl)-2-phenylacetylenes in glacial acetic acid in the presence of equimolar amount of perchloric acid under heating (90–115°C) was used to prepare 6-anilino-2-(acylmethyl)-2-phenyl-4-(phenylimino)-4H-1,3-dithiinium perchlorates in good yields.
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