Ring polymers in melts and solutions: scaling and crossover |
| |
Authors: | Sakaue Takahiro |
| |
Institution: | Department of Physics, Kyushu University, Fukuoka, Japan. sakaue@phys.kyushu-u.ac.jp |
| |
Abstract: | We propose a simple mean-field theory for the structure of ring polymer melts. By combining the notion of topological volume fraction and a classical van der Waals theory of fluids, we take into account many-body effects of topological origin in dense systems. We predict that although the compact statistics with the Flory exponent ν=1/3 is realized for very long chains, most practical cases fall into the crossover regime with the apparent exponent ν?2/5 during which the system evolves toward a topological dense-packed limit. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|