C-H bond arylations and benzylations on oxazol(in)es with a palladium catalyst of a secondary phosphine oxide |
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| Authors: | Ackermann Lutz Barfüsser Sebastian Kornhaass Christoph Kapdi Anant R |
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| Affiliation: | Institut fu?r Organische und Biomolekulare Chemie, Georg-August-Universita?t, Tammannstrasse 2, 37077 Go?ttingen, Germany. Lutz.Ackermann@chemie.uni-goettingen.de |
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| Abstract: | An air-stable, well-defined palladium complex derived from secondary phosphine oxide (SPO) (1-Ad)(2)P(O)H enabled efficient C-H bond functionalizations with ample scope, which set the stage for direct arylations and benzylations of (benz)oxazoles, as well as unprecedented palladium-catalyzed C-H bond arylations on nonaromatic oxazolines. |
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