Unusual cleavage of phenacyl-substituted benzimidazolium salts. Synthesis of 1,4-diarylimidazoles |
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Authors: | T. A. Kuz'menko V. V. Kuz'menko A. M. Simonov M. S. Korobov S. A. Filippov |
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Affiliation: | (1) Scientific-Research Institute of Physical and Organic Chemistry, Rostov State University, 344006 Rostov-on-Don |
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Abstract: | The action of ammonium acetate in acetic acid on 1-alkyl(aralkyl)-3-phenacylbenzimidazolium bromides leads, in addition to the formation of a new imidazole ring, to cleavage of the benzimidazole fragment of the molecule at the 1,2 bond to give 1-alkyl(aralkyl)aminoaryl-4-arylimidazoles. 1,2-Dimethyl-3-(p-nitrophenacyl)benzimidazolium bromide is converted under similar conditions to the corresponding 2-methylimidazole. 4,4-Dimethyl-2,2-bis(p-nitrophenyl)-1,1-dipyrrolo[1,2-a]benzimidazole was isolated as a side product of this reaction.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 388–392, March, 1982. |
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