Formation of fullerene dianions in a Penning trap

Fullerene dianions in the range C₇₀^2- to C₉₀^2- have been created by subjecting trapped fullerene monoanions to low energy electrons in a Penning trap. The dianion production was found to be a function of the trapping-potential depth and the time of interaction between the simultaneouslystored monoanionsand electrons. Under similar conditions the dianion yield depends on the size ofthefullerenes with more than 10% of the trapped C₉₀^- ions forming dianions while the corresponding relative yield for C₇₀^2- was less than 0.1%. The large difference can be explained by the repulsive Coulomb barrierand the second electron affinity of the fullerenes.