Liquid-crystalline hybrid materials based on [60]fullerene and bent-core structures |
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| Authors: | Vergara Jorge Barberá Joaquín Serrano José Luis Ros M Blanca Sebastián Nerea de la Fuente Rosario López David O Fernández Gustavo Sánchez Luis Martín Nazario |
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| Institution: | Dpto. Química Orgánica, Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza, C.S.I.C., 50009-Zaragoza, Spain. |
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| Abstract: | What a core-ker! By the appropriate combination of promesogenic bent-core structures and the C(60) unit, lamellar polar liquid-crystal phases were induced. The supramolecular organization of the functional fullerene-based assemblies, the temperature range of the soft phase, the stabilization of the mesophase-like order at room temperature, and the molecular switching under an electric field can be tuned, depending on the molecular structure. |
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| Keywords: | fullerenes liquid crystals molecular electronics organic functional materials supramolecular chemistry |
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