Catalytic asymmetric diastereodivergent deracemization |
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Authors: | Luparia Marco Oliveira Maria Teresa Audisio Davide Frébault Frédéric Goddard Richard Maulide Nuno |
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Institution: | Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany. |
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Abstract: | Your wish is my command: Deracemization is a powerful strategy wherein a racemate is converted into a 100?% yield of a single enantiopure product. A new concept in catalytic deracemization is presented, in which a racemate with n?stereogenic elements can be selectively converted into each one of 2(m) (m = number of chiral centers of the product) different enantiopure products, by simple tuning of the reaction conditions. |
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Keywords: | azlactone cyclobutene deracemization diastereodivergent palladium |
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