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Catalytic asymmetric diastereodivergent deracemization
Authors:Luparia Marco  Oliveira Maria Teresa  Audisio Davide  Frébault Frédéric  Goddard Richard  Maulide Nuno
Institution:Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 45470 Mülheim an der Ruhr, Germany.
Abstract:Your wish is my command: Deracemization is a powerful strategy wherein a racemate is converted into a 100?% yield of a single enantiopure product. A new concept in catalytic deracemization is presented, in which a racemate with n?stereogenic elements can be selectively converted into each one of 2(m) (m = number of chiral centers of the product) different enantiopure products, by simple tuning of the reaction conditions.
Keywords:azlactone  cyclobutene  deracemization  diastereodivergent  palladium
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