Oxidative properties of [1,2-b]selenophenes and 4H-selenochromenes and their interaction with hydrogen sulfide |
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Authors: | E. V. Shinkar’ A. V. Okhlobystina A. O. Okhlobystin N. T. Berberova V. F. Abdulaeva |
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Affiliation: | 1. Astrakhan State Technical University, ul. Tatishcheva 16, Astrakhan, 4114025, Russia
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Abstract: | Electrochemical behavior of [1,2-b]selenophenes and 4H-selenochromenes in organic media and their interaction with hydrogen sulfide have been studied. In aprotic solvents (CH2Cl2 and CH3CN), the organoselenium compounds are oxidized at anode to give cation-radicals. In the presence of hydrogen sulfide, at its oxidation potential (1.60 V) [1,2-b]selenophenes and 4H-selenochromenes undergo recyclization into corresponding thiophenes and thiochromenes. The recyclization yielding sulfur analogs have been studied in the presence of organic electromediators, including the transition metal complex with redox-active ligands, as well. |
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