| Cu(Ⅱ)及Zn(Ⅱ)与直链醚席夫碱配合物的合成与表征 |
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| 引用本文： | 吴静,沈联芳.Cu(Ⅱ)及Zn(Ⅱ)与直链醚席夫碱配合物的合成与表征[J].波谱学杂志,1998,15(4):335-341. |
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| 作者姓名： | 吴静 沈联芳 |
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| 作者单位： | 1. 浙江大学化学系, 杭州 310027;2. 中国科学院武汉物理与数学研究所波谱与原子分子物理国家重点实验室, 武汉 430071 |
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| 基金项目： | 国家自然科学基金(29671026)、浙江省自然科学基金(296062)和中科院波谱与原子分子物理国家重点实验室(971502)资助项目. |
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| 摘 要： | 合成了两种直链醚席夫碱双水杨醛缩二甘醇二胺(SALDA)和双水杨醛缩四甘醇二胺(SALTTA)及其新配合物Zn(SALDA)](NO3)2·4H2O和Cu3(SALTTA)(NO3)4](NO3)2·3H2O.并以IR谱、UV谱,特别是1H和13C NMR谱等方法进行了表征,并详细地讨论了合成方法,IR谱表明SALTTA中醚氧并未全部配位.
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| 关 键 词： | 直链醚 席夫碱配合物 合成 IR NMR |
| 收稿时间： | 1998-02-19 |
SYNTHESIS AND CHARACTERIZATION OF Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES WITH NONCYCLIC POLYETHER SCHIFF BASES |
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| Wu Jing,and Yao Kemin.SYNTHESIS AND CHARACTERIZATION OF Cu(Ⅱ) AND Zn(Ⅱ) COMPLEXES WITH NONCYCLIC POLYETHER SCHIFF BASES[J].Chinese Journal of Magnetic Resonance,1998,15(4):335-341. |
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| Authors: | Wu Jing and Yao Kemin |
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| Institution: | 1. Department of Chemistry, Zhejang University, Hangzhou 310027, China;3. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Phys. & Math., The Chinese Academy of Sciences, Wuhan 430071, China |
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| Abstract: | Two kinds of noncyclic polyether Schiff bases, bis salicylidene diethylene glycol diamine (SALDA) and bis salicylidene tetraethylene glycol diamine (SALTTA) as well as their new complexes Zn(SALDA) (NO 3) 2\54H 2O and Cu 3(SALTTA)(NO 3) 4 (NO 3) 2\53H 2O have been synthesized and characterized by IR and UV spectra, especially by 1H and 13 C NMR methods. Synthesis method has been studied in detail. IR spectra show that not all of the ethereal oxygen donor atoms in SALTTA are coordinated to the central metal ions. |
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| Keywords: | Non cyclic polyether Schiff base complex Synthesis IR NMR |
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