Untersuchungen über das Gleichgewicht des Hg2+-Hg 2 2+ -Hg-Systems in konzentrierten Perchloratlösungen |
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| Authors: | Ewa Malyszko Jan Malyszko |
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| Affiliation: | 1. Institut für Chemie, P?dagogische Hochschule, PL-25020, Kielce, Polen
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| Abstract: | The formal potentials of the Hg2+/Hg 2 2+ , Hg 2 2+ /Hg and Hg2+/Hg redox couples and the apparent equilibrium constants of the reaction Hg2+ + Hg ∝ Hg 2 2+ in conc. aqueous solutions of Mg(ClO4)2 and Ca(ClO4)2 have been determined from emf measurements performed using cells with liquid junction. Based on these data, the hydration numbers of the Hg2+ and Hg 2 2+ ions were estimated. |
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