Untersuchungen über das Gleichgewicht des Hg2+-Hg 2 2+ -Hg-Systems in konzentrierten Perchloratlösungen |
| |
Authors: | Ewa Malyszko Jan Malyszko |
| |
Affiliation: | 1. Institut für Chemie, P?dagogische Hochschule, PL-25020, Kielce, Polen
|
| |
Abstract: | The formal potentials of the Hg2+/Hg 2 2+ , Hg 2 2+ /Hg and Hg2+/Hg redox couples and the apparent equilibrium constants of the reaction Hg2+ + Hg ∝ Hg 2 2+ in conc. aqueous solutions of Mg(ClO4)2 and Ca(ClO4)2 have been determined from emf measurements performed using cells with liquid junction. Based on these data, the hydration numbers of the Hg2+ and Hg 2 2+ ions were estimated. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |
|