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Monochromatic‐red‐light emission of novel copolymers containing carbazole units and europium–acrylate complexes
Authors:Mujie Yang  Qidan Ling  Markus Hiller  Xizhi Fun  Xu Liu  Lianhui Wang  Wengong Zhang
Abstract:Nearly monochromatic‐red‐light‐emitting polymers with pendant carbazole and europium (Eu) complex were synthesized and characterized by Fourier transform infrared, elemental analysis (EA), 1H NMR, 13C NMR, UV, and gel permeation chromatography. The photoluminescence and electroluminescence (EL) properties of these polymers were investigated. A single‐layer light‐emitting‐diode device of the structure (indium tin oxide/polymer P4/Al) was fabricated, showing the characteristic bright‐red EL of the Eu3+ complex at 614 nm at a turn‐on voltage of about 17 V. The EL spectrum, current–voltage, and emission‐intensity–voltage characteristics of the device were measured. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 3405–3411, 2000
Keywords:polymer  photoluminescence  electroluminescence  light‐emitting diode  europium complex
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