| 钒氧配合物[VOL(C9H6NO)]·CH2Cl2的合成与晶体结构 |
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| 引用本文： | 邓兆鹏,高山,赵辉,霍丽华.钒氧配合物[VOL(C9H6NO)]·CH2Cl2的合成与晶体结构[J].无机化学学报,2007,23(1):173-176. |
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| 作者姓名： | 邓兆鹏 高山 赵辉 霍丽华 |
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| 作者单位： | 黑龙江大学化学化工与材料学院功能材料室,哈尔滨,150080 |
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| 基金项目： | 黑龙江省自然科学基金;黑龙江省高校骨干教师计划 |
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| 摘 要： | A oxovanadium(Ⅴ) complex of VOL(C9H6NO)]·CH2Cl2H2L=2-hydroxy-1-naphthaldehyde 4-methoxy-benzoylhydrazone, C9H6NO-=8-hydroxyquinoline anion] has been synthesized and characterized by elemental analyses, IR and single crystal X-ray diffraction. The crystal crystallizes in triclinic system, the space group is P1, with the crystal cell parameters a=1.087 0(2) nm, b=1.107 1(2) nm, c=1.269 3(3) nm, α=67.84(3)°, β=79.26(3)°, γ=73.85(3)° and V=1.353 1(6) nm3 , Mr=614.34, R=0.0503, wR=0.1409. The V(Ⅴ) atom is six-coordinated by one O atom of oxo group, two O atoms and one N atom of the tridentate hydrazone ligand, as well as one N atom and one O atom of 8-hydroxyquinoline ligand, thus defining a distorted octahedral VO(ONO)(NO) geometry. A two-dimensional supramolecular layer structure is formed through π-π stacking interactions. CCDC: 268672.
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| 关 键 词： | 钒氧配合物 腙 合成 晶体结构 |
| 文章编号： | 1001-4861（2007）01-0173-04 |
| 修稿时间： | 2006-08-02 |
Synthesis and Crystal Structure of the Oxovanadium(Ⅴ) Complex [VOL(C9H6NO)]·CH2Cl2 |
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| DENG Zhao-Peng,GAO Shan,ZHAO Hui and HUO Li-Hua.Synthesis and Crystal Structure of the Oxovanadium(Ⅴ) Complex [VOL(C9H6NO)]·CH2Cl2[J].Chinese Journal of Inorganic Chemistry,2007,23(1):173-176. |
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| Authors: | DENG Zhao-Peng GAO Shan ZHAO Hui and HUO Li-Hua |
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| Institution: | Laboratory of Functional Materials, School of Chemistry and Materials Science, HeilongJiang University, Harbin 150080,Laboratory of Functional Materials, School of Chemistry and Materials Science, HeilongJiang University, Harbin 150080,Laboratory of Functional Materials, School of Chemistry and Materials Science, HeilongJiang University, Harbin 150080 and Laboratory of Functional Materials, School of Chemistry and Materials Science, HeilongJiang University, Harbin 150080 |
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| Abstract: | A oxovanadium(Ⅴ) complex of VOL(C9H6NO)] ·CH2Cl2 H2L=2-hydroxy-1-naphthaldehyde 4-methoxybenzoylhydrazone, C9H6NO-=8-hydroxyquinoline anion] has been synthesized and characterized by elemental analyses, IR and single crystal X-ray diffraction. The crystal crystallizes in triclinic system, the space group is P1,with the crystal cell parameters a=1.087 0(2) nm, b=1.107 1(2) nm, c=1.269 3(3) nm, α=67.84(3)°, β=79.26(3)°,γ=73.85(3)° and V=1.353 1(6) nm3, Mr=614.34, R=0.0503, wR=0.1409. The V(Ⅴ) atom is six-coordinated by one O atom of oxo group, two O atoms and one N atom of the tridentate hydrazone ligand, as well as one N atom and one O atom of 8-hydroxyquinoline ligand, thus defining a distorted octahedral VO(ONO)(NO) geometry. A twodimensional supramolecular layer structure is formed through π-π stacking interactions.CCDC:268672. |
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| Keywords: | hydrazone synthesis crystal structure |
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