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Catalytic tritiation studies using tritium NMR spectroscopy
Authors:E A Evans  D C Warrell  J A Elvidge  J R Jones
Institution:(1) Amersham International Limited, HP7 9LL Amersham, Bucks, England;(2) Chemistry Department, University of Surrey, GU2 5XH Guildford, England
Abstract:The development of tritium nuclear magnetic resonance spectroscopy now makes it possible to determine the tritium distribution in virtually any organic compound at the millicurie level of radioactivity. Results of catalytic experiments show that in some cases a remarkable degree of specificity can be achieved when using procedures that are expected to produce generally labelled compounds. Conversely there are instances where specific labelling procedures are less than 100% successful.
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