Organocatalyzed cycloaddition of carbon dioxide to aziridines |
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| Authors: | Yichen WuGuosheng Liu |
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| Institution: | State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, Shanghai 200032, China |
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| Abstract: | An efficient and simple process for the fixation of carbon dioxide (CO2) to aziridine for the synthesis of 2-oxazolidinone by using DBN as catalyst, LiI as an additive under atmospheric pressure was developed. This chemical fixation of CO2 could also be carried out at room temperature with prolonged reaction time. |
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