Synthesis of azines in solid state: reactivity of solid hydrazine with aldehydes and ketones |
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Authors: | Lee Byeongno Lee Kyu Hyung Cho Jaeheung Nam Wonwoo Hur Nam Hwi |
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Institution: | Department of Chemistry, Sogang University, Seoul 121-742, Korea. |
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Abstract: | Highly conjugated azines were prepared by solid state grinding of solid hydrazine and carbonyl compounds such as aldehydes and ketones, using a mortar and a pestle. Complete conversion to the azine product is generally achieved at room temperature within 24 h, without using solvents or additives. The solid-state reactions afford azines as the sole products with greater than 97% yield, producing only water and carbon dioxide as waste. |
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