Total synthesis of polygalolide A |
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| Authors: | Adachi Masaatsu Yamada Hitomi Isobe Minoru Nishikawa Toshio |
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| Affiliation: | Laboratory of Organic Chemistry, Graduate School of Bioagricultural Sciences, Nagoya University, Chikusa, Nagoya 464-8601, Japan. madachi@agr.nagoya-u.ac.jp |
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| Abstract: | The total synthesis of polygalolide A was accomplished through intramolecular C-glycosylation of glucal modified with siloxyfuran. The siloxyfuran group and siloxy substituent at the C-3 position played crucial roles in allowing direct access to the highly substituted oxabicyclo[3.2.1] core skeleton with correct quaternary stereogenic centers. |
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