Reactions on a solid surface. A simple, economical, and efficient acylation of alcohols and amines over Al2O3 |
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| Authors: | Yadav Veejendra K Ganesh Babu K |
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| Institution: | Department of Chemistry, Indian Institute of Technology, Kanpur-208 016, India. vijendra@iitk.ac.in |
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| Abstract: | Al(2)O(3) brings about a rapid acylation of a range of alcohols and amines with acid chlorides and acid anhydrides, respectively. Amines are easily Boc- and Cbz-protected on reaction with Boc-anhydride and Cbz-Cl, respectively. The acylation of phenols is slow enough to allow chemoselective acylation of alcohols and amines in the presence of phenols. |
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