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Electric‐Field‐Induced Viscosity Change of a Nematic Liquid Crystal with Gold Nanoparticles
Authors:Dr Kosuke Kaneko  Yoshihiro Ujihara  Kodai Oto  Prof Dr Takeshi Hashishin  Prof Dr Tomonori Hanasaki
Institution:1. Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University, 1‐1‐1, Nojihigashi, Kusatsu, Shiga 525‐8577 (Japan);2. Graduate School of Science and Technology, Kumamoto University, 2‐39‐1 Kurokami, Chuo‐ku, Kumamoto 860‐8555 (Japan)
Abstract:The electro‐rheological (ER) effect of a composite material consisting of a nematic liquid crystal (LC) and gold nanoparticles covered with mesogenic groups is discussed. The gold nanoparticles are covered by alkyl chains and liquid‐crystalline compounds. The influences of the alkyl‐chain length and the coverage by the alkyl chain and the mesogenic group on the miscibility of the nanoparticles with the LC are investigated by polarizing optical microscopy (POM). The presence of the gold nanoparticles in the nematic LC (5CB) leads to an enhanced ER response compared to that observed for 5CB. The prominent ER effect observed in this study is supported by the two mechanisms proposed, that is, the homogeneous and heterogeneous mechanisms. This study demonstrates the potential of a hybrid system consisting of an LC and gold nanoparticles to improve the ER effect.
Keywords:electro‐rheological effect  gold nanoparticles  liquid crystals  materials science  viscosity
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