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Enhanced Activity of CuCeO Catalysts for CO Oxidation: Influence of Cu2O and the Dispersion of Cu2O,CuO, and CeO2
Authors:Dr Zhenhua Wang  Dr Ren Li  Prof Qianwang Chen
Institution:1. Hefei National Laboratory for Physical Sciences at Microscale, Department of Materials Science & Engineering & Collaborative Innovation Center of Suzhou Nano Science and Technology, University of Science and Technology of China, Hefei (China);2. High Magnetic Field Laboratory, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei (China)
Abstract:CuCeO catalysts prepared by a hydrothermal method with subsequent calcination are tested for the catalytic oxidation of CO. This synthesis method leads to a homogeneous dispersion of Cu2O, CuO, and CeO2 in the catalysts. The composition of the catalysts is determined by the molar ratio of the metals, the hydrothermal process, and calcination temperature and influences the catalytic performance. The catalyst containing Cu2O exhibits high catalytic activity with almost 100 % CO conversion at 105 °C and shows excellent stability with the conversion ratio not decreasing after four months of storage.
Keywords:carbon monoxide  copper  cerium  heterogeneous catalysis  hydrothermal synthesis
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