Dichlorosilylene: Rate constant for the gas-phase reaction with nitric oxide |
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| Authors: | V. Sandhu I. Safarik O. P. Strausz T. N. Bell |
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| Affiliation: | 1. Department of Chemistry, University of Alberta, T6G 2G2, Edmonton, Alberta, Canada
2. Department of Chemistry, Simon Fraser University, V5A 1S6, Burnaby, British Columbia, Canada
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| Abstract: | Using the recently detected intense UV absorption spectrum of it has been established that SiCl2 reacts with nitric oxide in the gas phase with a bimolecular rate constant, k(SiCl2+NO), of (1.6±0.1)×109 M−1s−1 at 25°C. |
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