| 取代基电子效应对芳基甲烷氧化缩合反应及产物的影响 |
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| 引用本文： | 卢俊瑞,王亚林,吕振波,尹宁,张桂芝,Lu Junrui,Wang Yalin,Lü Zhenbo,YIN Ning,Zhang Guizhi. 取代基电子效应对芳基甲烷氧化缩合反应及产物的影响[J]. 化学通报, 2001, 64(5): 293-295 |
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| 作者姓名： | 卢俊瑞 王亚林 吕振波 尹宁 张桂芝 Lu Junrui Wang Yalin Lü Zhenbo YIN Ning Zhang Guizhi |
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| 作者单位： | [1]天津理工大学生物及化工学院，天津300191 [2]天津医科大学，天津300052 |
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| 基金项目： | 天津市自然科学基金!项目 (97370 16 11) |
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| 摘 要： | 研究了数种芳基甲烷在有机溶剂中碱催化下的氧化缩合反应，并对反应产物进行了表征，结果表明，芳基甲烷中取代基的吸电子效应影响其氧化缩合反应活性及产物结构特征，取代基吸电性越强，吸电基越多，氧化缩合越易发生，
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| 关 键 词： | 芳基甲烷 氧化缩合反应 电子效应 产物特性 取代基 |
| 修稿时间： | 2000-01-09 |
Influence of the Electron-effects of Substituents on Oxidative Demerization of Aryl Methanes and Properties of Products |
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| Lu Junrui,Wang Yalin,YIN Ning,Zhang Guizhi. Influence of the Electron-effects of Substituents on Oxidative Demerization of Aryl Methanes and Properties of Products[J]. Chemistry, 2001, 64(5): 293-295 |
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| Authors: | Lu Junrui Wang Yalin YIN Ning Zhang Guizhi |
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| Abstract: | Oxidative dimerizations of a seris of aryl methanes have been investigated and the products characterized.It is showed that,the reaction conditions of aryl methanes,the structures and properties of the products are affected by the electron effects of the substituting groups of the aryl methanes.With the increase of the ability to withdraw electron and the amount of the electron withdrawing groups,the oxidative dimerization proceeds easily. |
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| Keywords: | Aryl methane Oxidative dimerization Electron effect Product property |
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