The He(I) photoelectron spectra of some γ-substituted Co(III) acetylacetonate complexes |
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| Authors: | Harry G Brittain Garo Horozoglu ADavid Baker |
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| Institution: | Department of Chemistry, Ferrum College, Ferrum, Virginia 24088 U.S.A.;Department of Chemistry, Queens College, Flushing, New York 11367 U.S.A. |
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| Abstract: | The He(I) photoelectron spectra of the complexes of Co(III) with acetylacetone and several derivatives are reported. The ionization potentials of metal-localized d-electrons and ligand π-orbitals are used to probe the extent of metal-to-ligand π-bonding and possible aromatic character in the chelate ring. |
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| Keywords: | Address correspondence to this author |
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