Photoelectron spectra of the gauche and trans conformers of 1,2-bromochloroethane |
| |
| Authors: | F Carnovale TH Gan JB Peel |
| |
| Institution: | Department of Physical Chemistry, and Research Centre for Electron Spectroscopy, La Trobe University, Bundoora, Victoria, 3083 Australia |
| |
| Abstract: | The HeI photoelectron spectra of the gauche and trans conformers of 1,2-bromochloroethane have been obtained by analysis of time-averaged spectra recorded at different temperatures. Variations in ionization potentials of the two conformers are consistent with data obtained from molecular orbital calculations. Analysis of a HEII spectrum and comparisons with the related molecules 1,2-dichloroethane and 1,2-dibromoethane shows that the ClBr non-bonded interactions include both through-bond and through-space contributions. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
