| 杂芳基硼化合物的合成 |
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| 引用本文： | 黄世文,单自兴,黄金昆,赵德杰. 杂芳基硼化合物的合成[J]. 武汉大学学报(理学版), 1999, 0(2) |
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| 作者姓名： | 黄世文 单自兴 黄金昆 赵德杰 |
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| 作者单位： | 武汉大学化学学院 |
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| 基金项目： | 国家自然科学基金,武汉市晨光青年科学基金 |
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| 摘 要： | 利用２－溴噻吩、镁屑、硼酸三正丁酯或三氟化硼乙醚室温下一锅反应分别合成了一噻吩基、二噻吩基硼酸，三噻吩基硼烷及其衍生物．利用５－甲基－２－呋喃基锂、２－苯并呋喃基锂与硼酸三正丁酯或三氟化硼乙醚低温下反应合成了几种含呋喃基硼化合物．利用烃基格氏试剂与噻吩基硼酸正丁酯低温下反应合成噻吩基烃基硼酸衍生物
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| 关 键 词： | 噻吩基硼化合物；5－甲基－2－呋喃基硼化合物；2－苯并呋喃基硼化合物；“一锅”格氏反应；锂试剂 |
Preparation of Heteroarylboron Compounds |
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| HUANG Shi wen,SHAN Zi xing,HUANG Jin kun,ZHAO De jie. Preparation of Heteroarylboron Compounds[J]. JOurnal of Wuhan University:Natural Science Edition, 1999, 0(2) |
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| Authors: | HUANG Shi wen SHAN Zi xing HUANG Jin kun ZHAO De jie |
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| Abstract: | thienyl boronic acid,di(2 thienyl)borinic acid,tri(2 thienyl) borane and their deriverates were prepared by one pot reaction between 2 bromothiophene,magnesium and boron trifluoride ether or tributyl borate at room temperature .5 Methyl 2 furanyl and 2 benzofuranyl boron compounds were obtained from the corresponding lithium reagents reacting with borontrifluoride ether or tributylborate at lower temperature. |
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| Keywords: | thienylboron compound 5 methyl 2 furanyl boron compound 2 benzofuranyl boron compound one pot Grignard reaction lithium reagent |
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