| 9-BBN还原1,7-辛二烯-3-醇的研究 |
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| 引用本文： | 钱长涛,刘开文.9-BBN还原1,7-辛二烯-3-醇的研究[J].有机化学,1983,3(4):267-269. |
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| 作者姓名： | 钱长涛 刘开文 |
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| 作者单位： | 中国科学院上海有机化学研究所，中国科学院上海有机化学研究所 |
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| 摘 要： | 本文报道了用9-BBN与1,7-辛二烯-3-醇进行硼氢化反应的结果。这个反应的区域选择性极低,除生成1-辛烯-3-醇(47％)外,同时还生成了7-辛烯-3-醇(41％)和辛醇-3(12％)。
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| 关 键 词： | 硼氢化作用 硼烷 醇 选择性 还原。 |
Hydroboration of 1,7-Octadien-3-ol by 9-Borabicyclo[3.3.1]nonane |
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| Qian Changtao,Liu Kaiwen.Hydroboration of 1,7-Octadien-3-ol by 9-Borabicyclo[3.3.1]nonane[J].Chinese Journal of Organic Chemistry,1983,3(4):267-269. |
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| Authors: | Qian Changtao Liu Kaiwen |
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| Institution: | Qian Changtao,Liu Kaiwen Shanghai Institute of Organic Chemistry,Academia Sinica |
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| Abstract: | 1,7-Octadien-3-ol was reduced by 9-borabicyclo3.3.1] nonane as
hydroboration reagent.The locoselectivity of hydroboration of 1,7-octadien-3-ol
by 9-BBN was very low.In addition to 1-octen-3-ol (47%),and 7-octen-3-ol
(41%),octanol-8(12%) was also produced. |
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| Keywords: | hydroboration borane alcohol selectivity reduction |
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