First total synthesis and structural reassignment of (-)-aplysiallene |
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| Authors: | Wang Jian Pagenkopf Brian L |
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| Affiliation: | Department of Chemistry, University of Western Ontario, 1151 Richmond Street, London, ON, N6A 5B7, Canada. |
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| Abstract: | The first total synthesis of (-)-aplysiallene has been completed in 16 steps and features a key sequential Mukaiyama aerobic oxidative cyclization to prepare the fused bis-THF core. The original stereochemical assignment has been revised as shown. |
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