| 新型有机二氟化硼配合物的合成及其荧光性能 |
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| 引用本文： | 杨曦,马儒政,夏敏.新型有机二氟化硼配合物的合成及其荧光性能[J].合成化学,2011,19(4):437-440. |
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| 作者姓名： | 杨曦 马儒政 夏敏 |
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| 作者单位： | 浙江理工大学,化学系,浙江,杭州,310018 |
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| 基金项目： | 浙江省自然科学基金资助项目(Y4100034); 浙江理工大学研究生创新科研基金资助项目(YCX-S10015) |
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| 摘 要： | 以2,4-二羟基苯乙酮为起始原料,经4步反应合成了新型的有机二氟化硼配合物:5-甲氧基.2-(2-喹啉基)苯酚二氟化硼(5),其结构经<'1>H NMR,<,13>C NMR和IR表征.UV和FL研究结果表明:5不仅具有良好的溶液荧光,也呈现明亮的固体荧光.
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| 关 键 词： | 5-甲氧基-2-(2-喹啉基)苯酚 二氟化硼配合物 合成 荧光性能 |
Synthesis and Fluorescent Properties of a Novel Difluoroborane Complex |
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| YANG Xi,MA Ru-zheng,XIA Min.Synthesis and Fluorescent Properties of a Novel Difluoroborane Complex[J].Chinese Journal of Synthetic Chemistry,2011,19(4):437-440. |
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| Authors: | YANG Xi MA Ru-zheng XIA Min |
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| Institution: | YANG Xi,MA Ru-zheng,XIA Min(Department of Chemistry,Zhejiang University of Science and Technology,Hangzhou 310018,China) |
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| Abstract: | A novel difluoroborane complex,5-methoxyl-2-(2-quinolyl)phenol-boron difluoride(5),was synthesized by a five-step reaction from 2,4-dihydroxyacetophenone.The structure was characterized by 1H NMR,13C NMR and IR.The fluorescent properties of 5 was investigated by UV and fluorescent spectra.The results showed that 5 exhibited fluorescence not only in its liquid state but also its solid state. |
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| Keywords: | 5-methyoxy-2-(quinolin-2-yl)phenol difluoroborane complex synthesis fluorescence property |
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