| 新型C10高碳糖的NMR和ESI-MS/MS研究 |
| |
| 引用本文： | 邹大鹏,康建勋,刘宏民,许卫超,张慧君,张碧. 新型C10高碳糖的NMR和ESI-MS/MS研究[J]. 波谱学杂志, 2004, 21(4): 397-403 |
| |
| 作者姓名： | 邹大鹏 康建勋 刘宏民 许卫超 张慧君 张碧 |
| |
| 作者单位： | 郑州大学,化学系,河南,郑州,450052;郑州大学,化学系,河南,郑州,450052;郑州大学,化学系,河南,郑州,450052;郑州大学,化学系,河南,郑州,450052;郑州大学,化学系,河南,郑州,450052;郑州大学,化学系,河南,郑州,450052 |
| |
| 摘 要： | 利用1,2-异丙基-5位苯甲酰基α-D-呋喃型木糖合成了具有潜在抗菌活性的C10高碳糖，检测了该化合物的1H、13C NMR和ESI-MS/MS图谱，确证了该化合物的结构，通过DEPT和1H-1H COSY，HMQC，HMBC等2D NMR技术对其1H和13C NMR数据进行了全归属和较详细的解析并探讨了其ESI-MS/MS质谱裂解规律.
|
| 关 键 词： | NMR 归属 ESI-MS/MS 高碳糖 |
| 文章编号： | 1000-4556(2004)04-0397-07 |
| 收稿时间： | 2004-03-02 |
| 修稿时间： | 2004-03-02 |
SYNTHESIS OF A NEW C10 HIGHER CARBON SUGAR AND ITS STRUCTURE ELUCIDATION BY NMR AND ESI-MS/MS |
| |
| ZOU Da-peng,KANG Jian-xun,LIU Hong-min,XU Wei-chao,ZHANG Hui-jun,ZHANG Bi. SYNTHESIS OF A NEW C10 HIGHER CARBON SUGAR AND ITS STRUCTURE ELUCIDATION BY NMR AND ESI-MS/MS[J]. Chinese Journal of Magnetic Resonance, 2004, 21(4): 397-403 |
| |
| Authors: | ZOU Da-peng KANG Jian-xun LIU Hong-min XU Wei-chao ZHANG Hui-jun ZHANG Bi |
| |
| Affiliation: | ZOU Da-peng,KANG Jian-xun,LIU Hong-min~*,XU Wei-chao,ZHANG Hui-jun,ZHANG Bi |
| |
| Abstract: | PDC is commonly used to oxidate the hydroxy residue in carbohydrates to produce the corresponding ketone. Treatment of 1, 2-isopropylidene-5-O-benzoyl-α-D-xylofuranose with PDC in CH2Cl2 usually yields ketone. It was found in this study, however, a new type higher carbon sugar was obtained when the solvent in the above reaction was changed. The structure of the new higher carbon sugar was elucidated by NMR and ESI-MS/MS. The complete assignment of 1H and 13C NMR chemical shifts of this compound was obtained using 2D NMR techniques, including 1H-1H COSY, HMQC and HMBC. |
| |
| Keywords: | NMR ESI-MS/MS |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《波谱学杂志》浏览原始摘要信息 |
|
点击此处可从《波谱学杂志》下载全文 |
|
