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Spontaneous Vesicle Formation in Mixed Aqueous Solution of Poly-tailed Cationic and Anionic Surfactants
作者姓名:王晓妮  张洁
作者单位:Wen Jun CHEN1,Gan Zuo LI1*,Li Min ZHAI2,Bo Qin LI3,Jun XU4,Rui XIA5 1Key Lab for Colloid and Interface Chemistry of State Education Ministry,Shandong University,Ji抧an 250100 2Department of Chemistry,Jinan University,Ji抧an 250014 3School of Medicine,Shandong University,Ji抧an 250012 4Research Institution of Jinling Petrochemical Corporation,Nanjing 210046 5Beijing Municipal Institute of Drug Control,Beijing 100035
基金项目:The work was supported by the Natural Science Foundation of China (No. 29903006 29973023).
摘    要:Spontaneous vesicles from the mixed queous solution of poly-talied cationic surfactant PTA and anionic surfactant AOT are firstly obtained.Vesicle formation and characterizations are demonstrated by negative-staining TEM and dynamic light scattering.A monodisperse vesicle system is obtained with a polydispersity of 0.082.Ultrasonication can promote the vesicle formation,Mechanism of vesicle formation is discussed from the viewpoint of molecular interaction.

关 键 词:混合水溶液  TEM  阴离子表面活性剂  动态光散射  胶体体系  表征  泡沫  单分散性

Spontaneous Vesicle Formation in Mixed Aqueous Solution of Poly-tailed Cationic and Anionic Surfactants
Wen Jun CHEN,Gan Zuo LI,Li Min ZHAI,Bo Qin LI,Jun XU,Rui XIA.Spontaneous Vesicle Formation in Mixed Aqueous Solution of Poly-tailed Cationic and Anionic Surfactants[J].Chinese Chemical Letters,2003,14(3):327-330.
Authors:Wen Jun CHEN  Gan Zuo LI  Li Min ZHAI  Bo Qin LI  Jun XU  Rui XIA
Abstract:Spontaneous vesicles from the mixed aqueous solution of poly-tailed cationic surfactant PTA and anionic surfactant AOT are firstly obtained. Vesicle formation and characterizations are demonstrated by negative-staining TEM and dynamic light scattering. A monodisperse vesicle system is obtained with a polydispersity of 0.082. Ultrasonication can promote the vesicle formation. Mechanism of vesicle formation is discussed from the viewpoint of molecular interaction.
Keywords:Vesicle  dynamic light scattering  negative-staining TEM  spontaneous formation    
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